Each movie has two villains: the first one ,who is obvious in all three, the second one ,who is believed to be good but later becomes/revealed as a villain.
- Batman Begins— Obvious villain: Scarecrow (Jonathan Crane)

2nd villain: Ra’s Al Ghul (initially introduced to us as Henri Ducard):

- The Dark Knight. Obvious villain: The Joker

2nd villain: Two-Face (Harvey Dent):

- The Dark Knight Rises— obvious villain:Bane

2nd villain :Talia al Ghul (introduced initially as Miranda Tate)

EDIT:—
As pointed out by Naveenkumar Seetimani ,there is a third villain in each of the movies:
- Batman Begins — Carmine Falcone

- The Dark Knight— Coleman Reese and/or (added by me) Lau


- The Dark Knight Rises: Jonathan Crane (again!)

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